[PP1-6-1] Structure and chemical-physical composition of Earth's atmosphere

The temperature and pressure profiles determine the atmospheric structure. The latter consists of four basic levels, considering the vertical variability of the temperature. These main four levels are troposphere, stratosphere, mesosphere, and thermosphere. In the troposphere (0-12km), which is the lowest layer of the atmosphere, all the meteorological processes that affect our everyday life take place. The lowest part of the troposphere is known as the boundary layer (0-3km), where all the surface-atmosphere interactions and exchanges take place. The troposphere concentrates the water vapor and 90% of atmospheric mass, while the chemical composition of all atmospheric layers consists of nitrogen, oxygen, argon and trace gases. The main parameters that characterize the atmosphere structure are pressure, density, and temperature. All the aforementioned parameters are related to the atmospheric composition and vary with altitude, latitude, longitude and season. Additionally, the stratosphere, which is the layer above the troposphere, contains almost all of the ozone abundance (~90%) of the atmosphere in a region named as ozone layer and traced between 15 and 35km. The interaction of the incoming solar radiation with ozone in this layer causes the reduction of the incoming harmful UV radiation provoking the temperature increase in the stratospheric layer. The 99.9% of total atmospheric mass is concentrated in lower atmosphere (<50km) with Nitrogen (N2, 78.08%), Oxygen (O2, 20.95%) and argon (Ar, 0.93%) being the major constituents of the atmosphere. Water vapor (H2O) is considered as a significant factor, too. Despite the fact that it depicts a very small amount of total atmospheric mass, it’s one of the most important greenhouse gases, along with carbon dioxide (CO2) and methane (CH4), absorbing the Earth’s longwave (infrared) radiation, affecting the energy balance of Earth-Atmosphere system. Furthermore, water vapor plays a decisive role in the formation of clouds and precipitation. Together with the basic chemical (atoms, molecules, ions) constituents of a "standard" atmosphere, aerosols of natural and anthropogenic origin have to be considered too, as far as the interaction of e.m. radiation with atmosphere is concerned.

External resources

  • Jacobson, M. Z., & Jacobson, M. Z. (2005). Fundamentals of atmospheric modeling. Cambridge university press.
  • Liou, K.N. (2002, 1980). An Introduction to Atmospheric Radiation. Academic Press - Second Edition.
  • Seinfeld, J. H., & Pandis, S. N. (2016). Atmospheric chemistry and physics: from air pollution to climate change. John Wiley & Sons.
  • Wallace, J. M., & Hobbs, P. V. (2006). Atmospheric science: an introductory survey (Vol. 92). Elsevier.

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